Position: Home > Articles > Mechanism on Adsorption Cu~(2+) by Crosslinked Carboxymethyl Konjac Glucomannan
Hubei Agricultural Sciences
2009,48
(1)
161-163
交联羧甲基魔芋葡甘聚糖吸附Cu~(2+)的机理
作 者:
王金玲;沈敏;瞿阳;薛爱芳;陈浩
单 位:
华中农业大学理学院;华中农业大学化学系
关键词:
交联羧甲基魔芋葡甘聚糖(CCMKGM);Cu2+;吸附机理
摘 要:
研究了CCMKGM对Cu2+的吸附热力学行为,用FTIR和RAMAN对吸附产物进行了结构表征,同时考察了不同解吸剂对吸附于CCMKGM上Cu2+解吸效果的影响。结果表明,CCMKGM主要以配位的形式吸附Cu2+;CCMKGM对Cu2+的吸附行为同时符合Langmuir和Freundlich等温方程;吸附为自发的、吸热的熵增加过程。
译 名:
Mechanism on Adsorption Cu~(2+) by Crosslinked Carboxymethyl Konjac Glucomannan
作 者:
WANG Jin-ling a,SHEN Min a,b,QU Yang a,XIE Ai-fang a,CHEN Hao a(a.Science College;b.Food Science and Technology College,Huazhong Agricultural University,Wuhan 430070,China)
关键词:
crosslinked carboxymethyl konjac glucomannan(CCMKGM);Cu2+;adsorption mechanism
摘 要:
In this paper the adsorption thermodynamics properties of CCMKGM with Cu2+ were investigated.The structure of adsorption products were characterized by the FTIR and RAMAN.The influence of different elution on desorption was stud-ied.The results showed that CCMKGM adsorbed Cu2+ mainly by complication,the experimental date fit well into the Lang-muir and Freundlich adsorption isotherm.The adsorption was a spontaneous endothermic process of increased entropy.