中国农业科学院农业信息研究所 中国农学会
Agricultural Information Institute of CAAS China Association of Agricultural Science Societies
En
Ch
中国农业科学院农业信息研究所 中国农学会 主办

AI检索

订阅

返回顶部
当前位置: 首页 > 文章 > 加速溶剂萃取-GC-MS检测土壤中萘及其取代衍生物 湖北农业科学 2019 (7) 108-110+121
Position: Home > Articles > Determination of naphthalene and its derivatives by using accelerated solvent extraction coupled with gas chromatography-mass spectrometry Hubei Agricultural Sciences 2019 (7) 108-110+121

加速溶剂萃取-GC-MS检测土壤中萘及其取代衍生物

作  者：
张莉;李科;刘佳;张辰凌
单  位：
中国地质科学院水文地质环境地质研究所监测中心
关键词：
土壤;萘及取代衍生物;加速溶剂萃取;气相色谱-质谱
摘  要：
建立了土壤中萘及其取代衍生物的加速溶剂萃取方法。土壤经石英砂分散后,装入加速溶剂萃取仪萃取池中,以二氯甲烷-丙酮(V/V,1∶1)为溶剂,在炉温100℃、压力10.3422 MPa条件下萃取10 min。萃取液经过K-D浓缩后,用氟罗里硅土小柱净化,用DB-5MS柱分离,以气相色谱-质谱定性定量检测。对空白土壤样品进行3种浓度水平的加标试验,其平均回收率为64.0%～102.6%,相对标准偏差为7.6%～15.2%。
译  名：
Determination of naphthalene and its derivatives by using accelerated solvent extraction coupled with gas chromatography-mass spectrometry
作  者：
ZHANG Li;LI Ke;LIU Jia;ZHANG Chen-ling;Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological Sciences;
关键词：
soil;;naphthalene and its derivatives;;accelerated solvent extraction;;GC-MS
摘  要：
A method that accelerated solvent extraction of naphthalene and its derivatives was carried out in this research. A soil sample, mixed with some silica sand, was placed in the extract cell. Objectives were extracted by dichloromethane-acetone(V∶V,1∶1) at extraction temperature of 100 ℃ and extraction pressure of 10.3422 MPa for 10 min. The eluent was purfied using florisil silica column after concentrated by K-D. Then naphthalene and its derivatives were analyzed by gas chromatography-mass spectrometry using a DB-5MS column. Spiked recoveries of three concentrations ranged from 64.0%～102.6% with relative standard deviation 7.6%～15.2%(n=7).

相似文章

导出引用
计量
文章访问数: 10
HTML全文浏览量: 0
PDF下载量: 0

所属期刊

推荐期刊

友情链接Friendly link
农业信息研究所Agricultural information institute 农业智能知识服务平台Agricultural intelligent knowledge service platform 农业学术服务平台Agricultural Knowledge Service System 中国知网CNKI 维普网VIP 万方WANFANG DATA
联系我们Contact us

电话Tell：010-82109652-808

邮箱E-mail：agrijournal@caas.cn

服务Service
关于我们About us 意见建议Opinions and suggest
版权说明Copyright
单位：中国农业科学院农业信息研究所 中国农学会 © 2017中国农业科学院农业信息研究所 ICP备案号：京ICP备09089781号-46