Junhong Deng;Xin Jiang;Xianguo Lü;Yu Guo;Fang Wang;Bin Zhan

State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China);Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China);Department of Food Science and Bioengineering, Bengbu College, Bengbu 233000 (China);State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China;State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China)

contact;atrazine;coeffcient;r2;nonlinear;freundlich equatio

A batch experiment was performed to investigate nonequilibrium adsorption behavior of atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) on a fluvo-aquic soil. The amount of atrazine sorbed increased with increasing adsorption contact periods. For a range of initial atrazine concentrations, the percentage of atrazine sorbed within 24 h ranged from 24% to 77% of the observed total amount sorbed for the longest contact period; when adsorption contact periods were more than 72 h, the deviations in curves fitted using a nonlinear Freundlich equation gradually became less. The opposite trend was observed for the atrazine concentrations in solution. The effect of adsorption contact periods on atrazine adsorption behavior was evaluated by interpreting the temporal variations in linear and nonlinear Freundlich equation parameters obtained from the phase-distribution relationships. As the adsorption contact period increased, the nonlinear Freundlich capacity coefficient k(f) showed a significant linear increase (r(2) = 0.9063, P < 0.001). However, a significant negative linear correlation was observed for the nonlinear coefficient n, a dimensionless parameter (r(2) = 0.5666, P < 0.05). Furthermore, the linear distribution coefficient k(d) ranged from 0.38 to 1.44 and exhibited a significant linear correlation to the adsorption contact period (r(2) = 0.72, P < 0.01). The parameters kf and n obtained from a time-dependent isotherm rather than the distribution coefficient kd estimated using the linear Freundlich equation were more appropriate to predict the herbicide residue in the field and thus more meaningful for environmental assessment.