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过硫酸铵引发阳离子淀粉接枝共聚物合成与表征

作  者:
吴修利;薛冬桦;王丕新
单  位:
中国科学院长春应用化学研究所生态环境高分子材料重点实验室;长春工业大学化学与生命科学学院;长春大学生物科学技术学院
关键词:
过硫酸铵;玉米淀粉;丙烯酰氧乙基三甲基氯化铵;阳离子聚合物;结构表征
摘  要:
采用水溶液聚合方法,以过硫酸铵(APS)为引发剂,将玉米淀粉(St)与丙烯酰氧乙基三甲基氯化铵(DAC)单体接枝聚合,制备阳离子淀粉高分子聚合物。讨论单体质量比、引发剂用量、反应温度和反应时间等因素对聚合物阳离子度的影响。结果表明:当加入淀粉质量1.0%的过硫酸铵,DAC与淀粉质量比2.5:1,50℃反应8h时,接枝共聚物的阳离子度最高可达53.68%。用红外光谱、扫描电镜、热失重分析对接枝共聚物结构进行表征,表征结果均证实阳离子淀粉高分子聚合物制备成功。
译  名:
Preparation by Ammonium Persulfate Initiation and Characterization of Cationic Starch Graft Copolymer
作  者:
WU Xiu-li1,XUE Dong-hua2,WANG Pi-xin3(1.College of Biological Science and Technology,Changchun University,Changchun 130012,China;2.School of Chemistry and Life Science,Changchun University of Technology,Changchun 130012,China;3.Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)
关键词:
ammonium persulfate;corn starch;acryloyloxyethyl trimethylammonium chloride(DAC);cationic polymer;structure characterization
摘  要:
A cationic polymer was synthesized by aqueous solution polymerization using corn starch and acyrloxyethyl trimethylammonium chloride(DAC) as the starting materials and ammonium persulfate as the initiator.The effects of the mass ratio between DAC and corn starch,initiator amount,temperature and reaction time on cationic degree(DC) were discussed.The results showed that the maximum DC reached 53.68% after 8 hours of the reaction at 50 ℃ between DAC and starch with a weight ratio of 2.5:1 initiated by ammonium persulfate added at a level of 1.0%(calculated on the basis of the weight of corn starch).Furthermore,the graft copolymer was structurally characterized by FTIR,scanning electron microscope(SEM) and thermo-gravimetric/differential thermal analyze(TG-DTA).

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