中国农业期刊集成服务平台

当前位置: 首页 > 文章 > 氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸在玉米植株及土壤上的残留分析方法农药 2017 (7) 502-505

Position: Home > Articles > Analysis of Fluroxypyr-meptyl and Fluroxypyr Residues in Corn Plant and Soil Agrochemicals 2017 (7) 502-505

氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸在玉米植株及土壤上的残留分析方法

作者：

王硕;侯志广;刘亚娟;刘良月;王博;赵晓峰;王鑫宏;梁爽;逯忠斌

单位：

吉林农业大学资源与环境学院

关键词：

氯氟吡氧乙酸异辛酯;氯氟吡氧乙酸;超高效液相色谱串联质谱;气相色谱;玉米植株;土壤

摘要：

[目的]建立气相色谱法和超高效液相色谱串联质谱法分别检测玉米植株和土壤中氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸残留的分析方法。[方法]植株和土壤中的氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸均经乙腈提取,氯氟吡氧乙酸异辛酯通过柱层析法净化,气相色谱仪检测;氯氟吡氧乙酸经QuEChERS法净化,利用超高效液相色谱-串联质谱(UPLC-MS/MS)测定,采用电喷雾负离子模式(ESI-),在多反应监测(MRM)模式下进行检测,基质匹配外标法定量。[结果]氯氟吡氧乙酸异辛酯在0.05~2.0 mg/L质量浓度范围内线性关系良好,相关系数为0.9997,在0.025~0.5 mg/L添加水平范围内,植株和土壤中的平均回收率为89.9%~100.6%,相对标准偏差为5.2%~10.2%,最低检出量为4.7×10~(-4)ng;氯氟吡氧乙酸在0.01~1.0 mg/L质量浓度范围内线性关系良好,相关系数为0.9995,在0.025~0.5 mg/kg添加水平范围内,植株和土壤的平均回收率为73.6%~92.8%,相对标准偏差为1.3%~9.4%,最低检出量为2.3×10~(-2)ng。[结论]建立方法的灵敏度、准确度和精确度均符合农药残留分析的要求,适用于玉米植株和土壤中氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸的检测和确证。

译名：

Analysis of Fluroxypyr-meptyl and Fluroxypyr Residues in Corn Plant and Soil

作者：

WANG Shuo;HOU Zhi-guang;LIU Ya-juan;LIU Liang-yue;WANG Bo;ZHAO Xiao-feng;WANG Xin-hong;LIANG Shuang;LU Zhong-bin;College of Resource and Environmental Science, Jilin Agricultural University;

关键词：

fluroxypyr-meptyl;;fluroxypyr;;ultra performance liquid chromatography-tandem mass spectrometry;;gas chromatography;;corn plant;;soil

摘要：

[Aims] A new method for analysis of fluroxypyr-meptyl and fluroxypyr residues in corn plant and soil by gas chromatography and ultra performance liquid chromatography-tandem mass spectrum respectively was developed.[Methods] The fluroxypyr-meptyl and fluroxypyr in corn plant and soil were extracted with acetonitrile.Fluroxypyr-meptyl was cleaned up by column chromatography and determined by GC. Fluroxypyr was purified by QuEChERS method, detected by UPLC-MS/MS under negative electrospray ionation(ESI-) and multiple reaction monitoring(MRM) mode with matrix matching and quantification of external standard method. [Results] The results showed that when the concentration ranged from 0.05 to 2.0 mg/L, the method for fluroxypyr-meptyl displayed good linearity with the correlation coefficient of 0.9997. When the fortified levels ranged from 0.025 to 0.5 mg/L, the average fortified recoveries were in the range of 89.9 to 100.6% and the relative standard deviations were in the range of 5.2 to10.2%, the limits of detection for fluroxypyr-meptyl was 4.7×10~(-4)ng. When the concentration ranged from 0.01 to 1.0 mg/L,the method for fluroxypyr displayed good linearity with the correlation coefficient of 0.9995. When the fortified levels ranged from 0.025 to 0.5 mg/L, the average fortified recoveries were in the range of 73.6 to 92.8% and the relative standard deviations were in the range of 1.3 to 9.4%, the limits of detection for fluroxypyr was 2.3 ×10~(-2)ng.[Conclusions] The method is simple and reliable, meets with the requirement for pesticide residue analysis, which is suitable for determination of fluroxypyr-meptyl and fluroxypyr in corn plant and soil.

相似文章

稻田苗后茎叶处理剂混用的联合除草作用 [郭文磊, 冯莉, 吴丹丹, 田兴山] 杂草学报 2020 (2) 75-78
炔草酯·唑草酮·氯氟吡氧乙酸异辛酯·解毒喹的气相色谱分析 [许艳秋, 安万霞, 王广成, 高立明, 李婷, 吴春先, 陈丙坤] 现代农药 2021 (6) 34-37
11.6%氯氟吡氧乙酸异辛酯·唑啉草酯乳油及安全剂解草酯分析方法研究 [黄亮, 金立] 世界农药 2021 (7) 38-42
HPLC-MS/MS法分析65%甲基磺草酮·氯氟吡氧乙酸异辛酯·莠去津可湿性粉剂含量 [黄玉贵, 林绍霞, 龚会琴, 陈迎丽, 何钰] 农药 2019 (8) 591-593,615
22%烟嘧·硝·氯吡OD高效液相色谱分析 [东琴, 潘静, 徐妍, 马超, 高敬雨, 刘润峰] 世界农药 2017 (1) 51-54
15%唑啉草酯·氯氟吡氧乙酸异辛酯可分散油悬浮剂高效液相色谱分析 [潘静, 徐妍, 傅杨, 东琴, 刘润峰, 高敬雨, 金鼎俊] 世界农药 2017 (3) 52-55
氯氟吡氧乙酸异辛酯防除结缕草草坪一年生阔叶杂草试验 [陈峰, 王俊, 付影, 陈峰晖, 卢筱青, 施旋, 刘向国] 南方农业 2018 (1) 8-9
15%唑啉草酯·氯氟吡氧乙酸异辛酯可分散油悬浮剂的研制 [高敬雨, 徐妍, 傅杨, 潘静, 东琴, 刘润峰, 韩忠良, 罗嵘] 现代农药 2017 (3) 17-20
一种防除林地杂草的混配除草剂田间药效评价 [易芬远, 李略, 梁唐敏, 罗家琪, 杨淑兰, 王超, 赖开平] 广西植保 2018,31 (1) 17-19
高效液相色谱法测定氯氟吡氧乙酸异辛酯的含量 [王海霞, 高晓晖] 农药 2014 (1) 31-33

导出引用

计量

文章访问数: 11

HTML全文浏览量: 0

PDF下载量: 0

氯氟吡氧乙酸异辛酯和氯氟吡氧乙酸在玉米植株及土壤上的残留分析方法

相似文章

所属期刊

农药

推荐期刊

世界农药

农药