当前位置: 首页 > 文章 > 低压离子色谱分离—次黄嘌呤增敏化学发光联用检测亚硫酸盐 食品科学 2006,27 (3) 185-188
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低压离子色谱分离—次黄嘌呤增敏化学发光联用检测亚硫酸盐

作  者:
沈祥;周光明;游水英;黄成;王莉;高智席
单  位:
西南师范大学化学化工学院
关键词:
低压离子色谱;化学发光;亚硫酸盐
摘  要:
本文发现次黄嘌呤对高锰酸钾-鲁米诺-SO3体系化学发光有增敏作用。结合低压离子色谱(LPIC)快速分离测定SO3,并用于实际样品中SO3含量测定。在优化条件下,SO3浓度与化学发光强度在5×10-8~4.8×10-6mol/L范围内成正比(r=0.9977),检出限3.2×10-8mol/L,选定SO3浓度为5×10-7mol/L,进行5次平行测定,RSD为3.25%。2-2-2-2-2-
译  名:
Sulfite Determination by Low Pressure Ion Chromatography with Chemiluminescence Sensitized by Hypoxzanthine
作  者:
SHEN Xiang,ZHOU Guang-ming*,YOU Shui-ying,HUANG Cheng,WANG Li,GAO Zhi-xi (School of Chemistry and Chemical Engineering, Southwest China NormalUniveristy, Chongqing 400715, China)
关键词:
sulfite;low pressure ion chromatography;chemiluminescence
摘  要:
Sulfite concentration is detected by low pressure ion chromatography (LPIC) with chemiluminescence due to thefact that hypoxanthine can sensitize the depression effect of sulfite on luminol- KMnO4 chemiluminescence reaction. The linerrange of sulfite concentration under optimal conditions is 5×10-8~4.8×10-6mol/L (r=0.9977)with a detection limit of 3.2×10-8mol/L, and RSD as 3.25% by assaying 5×10-7mol/L for five times. This simple, rapid and sensitive method is successfullyapplied to sulfite determination in food samples.

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