译 名:
Sulfite Determination by Low Pressure Ion Chromatography with Chemiluminescence Sensitized by Hypoxzanthine
作 者:
SHEN Xiang,ZHOU Guang-ming*,YOU Shui-ying,HUANG Cheng,WANG Li,GAO Zhi-xi (School of Chemistry and Chemical Engineering, Southwest China NormalUniveristy, Chongqing 400715, China)
关键词:
sulfite;low pressure ion chromatography;chemiluminescence
摘 要:
Sulfite concentration is detected by low pressure ion chromatography (LPIC) with chemiluminescence due to thefact that hypoxanthine can sensitize the depression effect of sulfite on luminol- KMnO4 chemiluminescence reaction. The linerrange of sulfite concentration under optimal conditions is 5×10-8~4.8×10-6mol/L (r=0.9977)with a detection limit of 3.2×10-8mol/L, and RSD as 3.25% by assaying 5×10-7mol/L for five times. This simple, rapid and sensitive method is successfullyapplied to sulfite determination in food samples.