当前位置: 首页 > 文章 > 对氯苯胺在湿地土壤中的吸附解吸特性 湖北农业科学 2009,48 (4) 78-81
Position: Home > Articles > Studies on the Adsorption and Desorption Actions of p-Chloroaniline in Wetland Soil Hubei Agricultural Sciences 2009,48 (4) 78-81

对氯苯胺在湿地土壤中的吸附解吸特性

作  者:
张志成;姚成;丁成;金建祥
单  位:
南京工业大学理学院;盐城工学院化学与生物工程学院
关键词:
对氯苯胺;吸附;解吸;湿地土壤
摘  要:
采用平衡振荡法研究对氯苯胺(PCA)在盐城湿地土壤中的吸附解吸过程,湿地土壤吸附动力学表明在1h之内吸附符合幂函数方程(qt=96.168t0.2158),1h后符合二级动力学方程(1/ct=0.06+0.0012t)。其解吸动力学过程的最优模型为幂函数方程(qt=14.585e0.2318t)。吸附等温线符合Freundlich方程(cs=21.38ce0.78)其吸附常数Kd=21.38,对土壤粒子有较大的亲和力。研究还发现PCA在湿地土壤中的吸附量与溶液pH值(pH值5~8)呈正相关,与溶液离子强度呈负相关。
译  名:
Studies on the Adsorption and Desorption Actions of p-Chloroaniline in Wetland Soil
作  者:
ZHANG Zhi-cheng1,YAO Cheng1,DING Cheng2,JIN Jian-xiang2,3 (1.College of Sciences, Nanjing University of Technology, Nanjing 210009,China; 2.School of Chemistry and Biology Engineering, Yancheng Institute of Technology,Yancheng 224003,Jiangsu,China; 3.Municipal Engineering Department, Southeast University, Nanjing 210000,China)
关键词:
p-Chloroaniline; adsorption; desorption; wetland soil
摘  要:
The adsorption and desorption course of p-Chloroaniline(PCA) on the wetland soil in Yancheng City were studied in this article. The results showed that power function equation(qt=96.168t0.215 8)and secondary equation(1/ ct=0.06+0.001 2t)were the best models for PCA adsorption on the soil in the first hour and one hour later,respectively. Power function equation (qt=14.585e0.231 8t)was the best models for PCA desorption. Adsorption isotherm of PCA on the soil was nonlinearity which could be described by Freundlich equation (cs=21.38ce0.78), adsorption equilibrium constant (Ka) was 21.38. The influence of the ionic strength and solution pH value on the adsorption of p-Chloroaniline also was researched. The results showed that adsorption was positively related to solution pH(pH=5~8), and was negatively related to ionic strength.

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