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Benzo[a]pyrene and Phenanthrene in Municipal Sludge from the Yangtze River Delta, China

作  者:
Shen Rong-yan;Yongming Luo;Sheng Feng;Gangya Zhang;Longhua Wu;Zhengao Li;Ying Teng;Peter Christi
单  位:
Department of Environment and Safety Engineering, Jiangsu Polytechnic University, Changzhou 213016 (China);Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China);Department of Agricultural and Environmental Science, Queen's University Belfast, Newforge Lane, Belfast BT9 5PX (UK; Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China);Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China)
关键词:
dw;sludge;sludge sample;municipal sludge;pa;4
摘  要:
To evaluate the contaminated conditions of benzo[a]pyrene (B[a]P) and phenanthrene (PA) in sludge and to ascertain whether B[a]P limit for land application of sludge exists, the contents of B[a]P and PA in 46 sludge samples from 15 cities in the Yangtze River Delta area of China were determined using high performance liquid chromatography (H PLC) coupled with a fluorescence detector after ultrasonic extraction and silica gel cleanup. B[a]P contents ranged from non-detectable to 1.693 mg kg(-1) dry weight (DW), averaged 0.402 mg kg(-1) DW, and were < 1.0 mg kg(-1) DW in most of the sludge samples. PA was found in all the sludge samples analyzed; its contents ranged between 0.028 and 1.355 mg kg(-1) DW, with an average value of 0.298 mg kg(-1) DW. Most of the sludge samples contained < 0.5 mg kg(-1) DW PA. All 46 municipal sludge samples analyzed in this study showed B[a]P contents < 3.0 mg kg(-1) DW, which is the limit value for sludge applied to agricultural lands in China. The contents and distributions of B[a]P and PA in municipal sludge were related to sludge types, sources and treatment technologies, along with the physical and chemical properties of these pollutants. Key Words: benzo[a]pyrene, municipal sludge, organic pollutants, phenanthrene, Yangtze River Delta

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