中国农业科学院农业信息研究所 中国农学会
Agricultural Information Institute of CAAS China Association of Agricultural Science Societies
En
Ch
中国农业科学院农业信息研究所 中国农学会 主办

AI检索

订阅

返回顶部
当前位置: 首页 > 文章 > 优化QuEChERS提取方法的液相色谱-串联质谱法测定马铃薯中砜嘧磺隆的残留量 农药 2018 (9) 658-661+681
Position: Home > Articles > Determination of the Rimsulfuron Residues in Potato by Modified QuEChERS Extraction Method and Liquid Chromatography-tandem Mass Spectrometry Agrochemicals 2018 (9) 658-661+681

优化QuEChERS提取方法的液相色谱-串联质谱法测定马铃薯中砜嘧磺隆的残留量

作  者：
张清涛;余雨蓉;王寿益;刘相吾;陈玉玲;卢平;胡德禹
单  位：
贵州大学精细化工研究开发中心教育部绿色农药与生物工程重点实验室
关键词：
砜嘧磺隆;马铃薯;Qu ECh ERS;正交试验设计
摘  要：
[目的]建立改进的Qu ECh ERS-液相色谱-串联质谱法测定砜嘧磺隆在马铃薯块茎、土壤及植株中残留的分析方法。[方法]基于单因素试验,采用正交设计优化Qu ECh ERS提取方法,确定砜嘧磺隆在马铃薯块茎、土壤及植株中的提取条件,对建立的方法进行验证。[结果]在优化后的Qu ECh ERS条件下,砜嘧磺隆在0.005~2.0 mg/L范围内线性关系良好,相关系数大于0.9996,检出限和定量限分别为0.17、0.50μg/kg。在3个基质中均出现基质增强效应。在添加水平为0.01~1.0 mg/kg范围内,平均回收率为86.36%~101.97%,相对标准偏差小于6.44%。[结论]该方法简单、快速、准确、灵敏度高,能应用于实际样品的检测。
译  名：
Determination of the Rimsulfuron Residues in Potato by Modified QuEChERS Extraction Method and Liquid Chromatography-tandem Mass Spectrometry
作  者：
ZHANG Qing-tao;YU Yu-rong;WANG Shou-yi;LIU Xiang-wu;CHEN Yu-ling;LU Ping;HU De-yu;Center For Research and Development of Fine Chemicals of Guizhou University, Key Laboratory of Green Pesticide and Bioengineering of Ministry of Education, Guizhou University;
关键词：
rimsulfuron;;potato;;QuEChERS;;orthogonal experiment
摘  要：
[Aims] A modified QuEChERS-liquid chromatography-tandem mass spectrometry method was developed to determine the rimsulfuron residues in potato tuber, soil and plant. [Methods] On the basis of single factor experiment,QuEChERS extraction method was optimized by orthogonal experiment to determine the extraction conditions of rimsulfuron in potato tuber, soil and plant, then the datas were verified. [Results] Under the modified extraction conditions, the linearity of rimsulfuron was good in the range of 0.005 to 2.0 mg/L with correlation coefficient of >0.9996.The limits of detection and limits of quantification were 0.17 and 0.50 μg/kg, respectively. Matrix enhancement effects were observed in three matrices. When the spiked levels were 0.01-1.0 mg/kg, the average recoveries of rimsulfuron in all matrices were 86.36-101.97% with relative standard deviations of <6.44%. [Conclusions] The established method is simple, rapid, accurate and sensitive, which can be applied on the residual analysis of rimsulfuron in actual samples.

相似文章

导出引用
计量
文章访问数: 11
HTML全文浏览量: 0
PDF下载量: 0

所属期刊

推荐期刊

友情链接Friendly link
农业信息研究所Agricultural information institute 农业智能知识服务平台Agricultural intelligent knowledge service platform 农业学术服务平台Agricultural Knowledge Service System 中国知网CNKI 维普网VIP 万方WANFANG DATA
联系我们Contact us

电话Tell：010-82109652-808

邮箱E-mail：agrijournal@caas.cn

服务Service
关于我们About us 意见建议Opinions and suggest
版权说明Copyright
单位：中国农业科学院农业信息研究所 中国农学会 © 2017中国农业科学院农业信息研究所 ICP备案号：京ICP备09089781号-46