中国农业科学院农业信息研究所 中国农学会
Agricultural Information Institute of CAAS China Association of Agricultural Science Societies
En
Ch
中国农业科学院农业信息研究所 中国农学会 主办

AI检索

订阅

返回顶部
当前位置: 首页 > 文章 > 水/油溶剂中酰胺基羧酸镁配合物的聚集性能研究 内蒙古农业大学学报(自然科学版) 2014 (5) 173-178
Position: Home > Articles > STUDY ON AGGREGATION PROPERTIES OF MAGNESIUM CARBOXYLATE COMPLEXES WITH AMIDE GROUP IN WATER / OIL SOLVENT Journal of Inner Mongolia Agricultural University(Natural Science Edition) 2014 (5) 173-178

水/油溶剂中酰胺基羧酸镁配合物的聚集性能研究

作  者：
斯钦德力根;那仁格日乐;白秀兰
单  位：
内蒙古师范大学物理与电子信息学院;内蒙古化工职业学院化学工程系;益海精细化学工业有限公司
关键词：
表面活性剂;金属配合物;聚集物
摘  要：
采用化学反应法,合成了镁配合物表面活性剂:辛酰丙氨酸镁和辛酰苯丙氨酸镁的混合物。在水/油溶剂中对镁配合物表面活性剂进行了电导率、核磁共振和粘度的测试,并研究了水对其聚集性质的影响。实验结果表明:在疏水有机溶液中,由于亲水-亲油平衡,镁配合物表面活性剂形成了聚集体。少量的水促进了溶解度的增加及聚集物的形成。通过增加水的含量,发现了在水-正己醇或水-环己醇等的混合溶液中,聚集体的结构发生了从逆胶束到双连续微乳液结构的转变。镁离子与配体之间强的相互作用主要反映在镁配合物表面活性剂的聚集行为特性上。
译  名：
STUDY ON AGGREGATION PROPERTIES OF MAGNESIUM CARBOXYLATE COMPLEXES WITH AMIDE GROUP IN WATER / OIL SOLVENT
作  者：
Siqin Deligen;Naren Gerile;Bai Xiu Lan;Department of Chemical Engineering,Inner Mongolia Vocational College of Chemical Engineering;College of Physics and Electronic Information,Inner Mongolia Normal University;Yihai Fine Chemical Industry Co. ,Ltd.;
关键词：
Surfactant;;metal complex;;aggregation
摘  要：
Magnesium complex surfactants were synthesized by using chemical methods in this paper,which was a mixture of octanoyl alanine magnesium and octanoyl phenylalanine magnesium. Conductivity,magnetic resonance and viscosity for magnesium complex surfactants were tested in the mixed solution of water and organic solvent,and the effects of water on its aggregation properties were studied. The results showed that the aggregates was formed on surfactant of the magnesium complex in a hydrophobic organic solvent due to the hydrophilic- lipophilic balance. A small amount of water can increase of the solubility for the complex and promoted the formation of the compound. It was found the structure of aggregates changed from reverse micelles to bicontinuous microemulsion by increasing the water content in the mixed solution of water / hexanol or water / cyclohexanol. The strong interaction between the magnesium ion and the ligand reflects in the aggregation behavior characteristics of the magnesium complex surfactant.

相似文章

导出引用
计量
文章访问数: 4
HTML全文浏览量: 0
PDF下载量: 0

所属期刊

推荐期刊

友情链接Friendly link
农业信息研究所Agricultural information institute 农业智能知识服务平台Agricultural intelligent knowledge service platform 农业学术服务平台Agricultural Knowledge Service System 中国知网CNKI 维普网VIP 万方WANFANG DATA
联系我们Contact us

电话Tell：010-82109652-808

邮箱E-mail：agrijournal@caas.cn

服务Service
关于我们About us 意见建议Opinions and suggest
版权说明Copyright
单位：中国农业科学院农业信息研究所 中国农学会 © 2017中国农业科学院农业信息研究所 ICP备案号：京ICP备09089781号-46